In 1972, Apollo astronaut Harrison Schmidt sniffed the air in his Lunar Module, the Challenger. "[It] smells like gunpowder in here," he said. His commander Gene Cernan agreed. "Oh, it does, doesn't it?"
The two astronauts had just returned from a long moonwalk around the Taurus-Littrow valley, near the Sea of Serenity. Dusty footprints marked their entry into the spaceship. That dust became airborne--and smelly.
Later, Schmidt felt congested and complained of "lunar dust hay fever." His symptoms went away the next day; no harm done. He soon returned to Earth and the anecdote faded into history.
http://science.nasa.gov/headlines/y2005/22apr_dontinhale.htm